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摘要
以石墨烯为导电基底,通过调控多巴胺的添加顺序,成功地制备了氮掺杂石墨烯负载Fe2O3复合材料。扫描电镜和透射电镜表征结果表明,平均尺寸约为20 nm的Fe2O3均匀分布在氮掺杂石墨烯片表面。所制备的氮掺杂石墨烯负载Fe2O3复合材料展现了良好的锂离子存储性能,在0.1 A/g的电流密度下首次放电容量可以达到1 434 mA·h/g,并在2 A/g下循环480次依然保持初始容量的78%。
Abstract
Fe2O3/nitrogen-doped graphene is produced through regulating the addition order of dopamine, with nitrogen-doped graphene as conductive substrate and dopamine as nitrogen source.It is verified through characterization by scanning and transmission electron microscopy that Fe2O3 nanoparticles with a size of around 20 nm are dispersed homogeneously on the surface of nitrogen-doped graphene.The prepared Fe2O3/nitrogen-doped graphene exhibits superior performance in Li storage with an initial discharge capacity reaching 1, 434 mAh·g-1 at a current density of 0.1 A·g-1, and shows a good cycling property with 78% capacity remained over 480 cycles at a current density of 2 A·g-1.
关键词
锂离子电池
/
Fe2O3
/
石墨烯
/
氮掺杂
/
负极材料
Key words
lithium-ion batteries
/
Fe2O3
/
graphene
/
nitrogen doping
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anode materials
氮掺杂石墨烯锚定Fe2O3用作锂离子电池高性能负极材料的研究[J].
现代化工, 2021, 41(11): 138-142,147 DOI:10.16606/j.cnki.issn 0253-4320.2021.11.029